The empirical formula for the compound is \(C_4H_4N_2O_2\).
Carbon: 48.98 g
Hydrogen: 4.12 g
Nitrogen: 14.27 g
Oxygen: 32.63 g
Convert the grams to moles using the molar masses:
Carbon: 48.98 g / 12.01 g/mol = 4.08 mol
Hydrogen: 4.12 g / 1.01 g/mol = 4.08 mol
Nitrogen: 14.27 g / 14.01 g/mol = 1.02 mol
Oxygen: 32.63 g / 16.00 g/mol = 2.04 mol
Divide each mole value by the smallest number of moles:
Carbon: 4.08 mol / 1.02 mol = 4
Hydrogen: 4.08 mol / 1.02 mol = 4
Nitrogen: 1.02 mol / 1.02 mol = 1
Oxygen: 2.04 mol / 1.02 mol = 2
A compound is a substance composed of two or more different types of atoms that are chemically bonded together in a specific ratio. These atoms may be from the same or different elements, and they are held together by chemical bonds such as ionic, covalent, or metallic bonds.
Compounds have unique properties that are different from their constituent elements, such as melting and boiling points, solubility, and reactivity. The properties of a compound are determined by its molecular structure, which is the arrangement of atoms and the types of bonds between them. Compounds can be formed through various chemical reactions such as synthesis, decomposition, and oxidation. They are essential to life as they make up the complex molecules found in living organisms, such as proteins, carbohydrates, and nucleic acids.
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Entropy increases when the degrees of freedom increases. Usually, if the number of molecules increases then the entropy increases. Predict the
ΔS for these chemical processes: Salt dissolves:
NaCl(s)→Na + (aq)+Cl − (aq)
A campire burns:
2C8H 18+25O2 → 16CO 2+18H2O
A metal forms a complex:
Ni2++3NH2CH 2CH2NH 2 (en) →[Ni( en )3] 2+
The Haber process to create ammonia for fertilizer:
N2 ( g)+3H2 ( g) → 2NH3 ( g)
Rust forms on a pipe:
Fe+3O2 → Fe3O4
The process of salt dissolving increases entropy because the solid NaCl has fewer degrees of freedom than the aqueous ions. Therefore, ΔS is positive.
The process of a campfire burning also increases entropy because the reactants, C8H18 and O2, have more degrees of freedom than the products, CO2 and H2O. Therefore, ΔS is positive.
The process of a metal forming a complex also increases entropy because the complex has more degrees of freedom than the individual metal ion and ligands. Therefore, ΔS is positive.
The Haber process to create ammonia for fertilizer also increases entropy because the reactants, N2 and H2, have more degrees of freedom than the product, NH3. Therefore, ΔS is positive.
The process of rust forming on a pipe also increases entropy because the reactants, Fe and O2, have more degrees of freedom than the product, Fe3O4. Therefore, ΔS is positive.
The ΔS for the mentioned chemical processes.
1. Salt dissolves: NaCl(s) → Na+(aq) + Cl−(aq)
ΔS is positive, as the solid salt dissolves into individual ions in the aqueous solution, leading to an increase in the degrees of freedom.
2. A campfire burns: 2C8H18 + 25O2 → 16CO2 + 18H2O
ΔS is positive, as the combustion of hydrocarbons increases the degrees of freedom due to the conversion of the reactants into gaseous products.
3. A metal forms a complex: Ni2+ + 3NH2CH2CH2NH2(en) → [Ni(en)3]2+
ΔS is negative, as the formation of a complex reduces the degrees of freedom by combining the metal ion with ligands.
4. The Haber process to create ammonia for fertilizer: N2(g) + 3H2(g) → 2NH3(g)
ΔS is negative, as the reactants have more degrees of freedom (4 molecules) than the products (2 molecules).
5. Rust forms on a pipe: Fe + 3O2 → Fe3O4
ΔS is negative, as the formation of solid rust from free atoms reduces the degrees of freedom.
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2. DETERMINE THE TEMPERATURE AT
WHICH NIO GRAMS OF POTASSIUM
NITRATE DISSOLVE IN 100 GRAMS OF
WATER
Answer:
20 degrees Celsius
Explanation:
carbon skeletons for amino acid biosynthesis are supplied by intermediates of the citric acid cycle (see the figure). which intermediate would you predict may directly supply the carbon skeleton for synthesis of a five-carbon amino acid?
The predicted intermediate that can directly supply the carbon skeleton for the synthesis of a five-carbon amino acid, is a-ketoglutarate. Correct answer: letter D.
This is because a-ketoglutarate is an intermediate of the Krebs cycle, and as such can directly supply the carbon skeleton for the synthesis of a five-carbon amino acid.
What is a-ketoglutarate?Five-carbon amino acids are essential for the synthesis of proteins in the body. a-Ketoglutarate is a key intermediate in the Krebs cycle that can directly supply the carbon skeleton for the synthesis of a five-carbon amino acid.
This makes a-ketoglutarate an important molecule for the synthesis of proteins in the body.
Which intermediate would you predict may directly supply the carbon skeleton for synthesis of a five-carbon amino acid?
Group of answer choices:
A) succinate
B) malate
C) cotrate
D) a-ketoglutarate
E) isocitrate
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Plastic is used to cover the copper wire in the power codes of appliances because plastic differs from copper in _________
Answer:
in copper from different plastics because appliances of codes to power day in wire copper the cover to use to plastic
For the following reaction at equilibrium in a reaction vessel, which change in the reaction will occur when the volume is increased? (Select all that apply.)P4 (s) + 6Cl2 (g) -> 4PCl3 (l)increase in Cl2shift to the rightincrease in PCl3more product producedshift to the left
Explanation:
At equilibrium, if the reaction vessel increases in volume, then the pressure will decrease, then the equilibrium will shift to the side with the most quantity of moles.
According to the reaction: P4 (s) + 6 Cl2 (g) => 4 PCl3 (l)
Gases are only considered here.
The statements that apply are:
increase in Cl2
shift to the left
Answer:
increase in Cl2
shift to the left
2. Which of the following is the best definition of half-life for a radioactive substance?
O A. Half of the amount of time required for all of the radioactive atoms to decay.
O B. The amount of time required for half of the radioactive atoms to decay.
O C. The amount of time required for each radioactive atom to decay halfway.
O D. All of the above.
Answer:
The amount of time required for each radioactive atom to decay halfway.
Explanation:
In radioactivity, which is the spontaneous emission of radiations from the nucleus of an unstable atom, each atom has a specific term called HALF-LIFE and is denoted by t1⁄2. Half-Life of an atom represents the amount of time it takes the nucleus of that atom to decay by half.
Therefore, based on the definitions given in the question, "The amount of time required for each radioactive atom to decay halfway" best describes HALF-LIFE.
- The first definition is wrong because it is NOT HALF THE AMOUNT OF TIME but half the amount of the atom while the second definition is wrong because it is NOT ALL THE ATOMS but a specific atom. Each atom has its own specific half-life.
50 g of NaF is added to 100 mL of water to form a solution. What is the concentration of the solution?
no ls eb vb vj lfn nbf, l mgñ rlr o
nepheline a nonpartisan that survives at room temperature can be used to protect wool clothing from being eaten by moths.
a) Explain in terms of intermolecular forces why Nephilim sublimes
b) Explain why Nathaline is not expected to dissolve in water
c) The empirical formula of naphthalene is C5H4 and the molecular mass of Nephilim is 128 g flash mole What is the molecular formula for Naphthalene
#1
Nephilim has very weak intermolecular forcesSo on heating it directly turns gas from solid.#2
Nathaline is non polar Water is polarSo it is not expected to dissolve in water.
#3
Empirical formula mass
5(12)+4=60+4=64gn:-
Molecular formula mass/Empirical formula mass128/642Molecular formula
n×Empirical formula2(C_5H_4)C_10H_8If a reactant is in excess, why do we not worry about the mole ratios involving that reactant?.
Answer: The limiting reactant will be used up first, meaning the reaction can no longer occur with only the excess reactant.
Explanation:
In a reaction the reactant which determines the yield of the reaction is called limiting reactant. Whereas, the reactant which is excess in amount does not itself lead the reaction after the limiting reactant is consumed.
What is excess reactant?In a reaction, the yield of the product depends on the number of moles of reactants. The reactants which is not sufficient in amount is determining the yield because as soon as this reactant is consumed, the production stopes.
The excess reactant on the other hand is excess in amount which can't lead the reaction alone after the consumption of the limiting reactant. Hence, we don't have to worry on the excess reactant.
The limiting reactant of a reaction can be determined by calculating the number of moles of each reactants participating in it.
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What are the 4 types of characterization?.
Answer:
There are actually five, and there's an easy way to remember them.
Physical Description
Action
Inner thoughts
Reactions
Speech
P.A.I.R.S
This will basically help you with any story you come up with
a chemical reaction is found to have a Keq of 29. What general statement can be made about the ratio of products to reactants in the solution of equilibrium?
A Keq value of 29 suggests that the products are strongly favored over the reactants at equilibrium, and the ratio of the concentration of products to the concentration of reactants is 29:1.
The equilibrium constant, Keq, for a chemical reaction is a measure of the relative concentrations of products and reactants at equilibrium. If the value of Keq for a reaction is greater than 1, it indicates that the products are favored at equilibrium, and if Keq is less than 1, it indicates that the reactants are favored. In the case of a Keq of 29, it suggests that the products are significantly favored over the reactants at equilibrium.
More specifically, the Keq value indicates the ratio of the concentration of products to the concentration of reactants at equilibrium. A Keq of 29 indicates that the concentration of products is 29 times greater than the concentration of reactants at equilibrium. This suggests that the reaction strongly favors the formation of products, and the equilibrium is shifted towards the products side.
It is important to note that the value of Keq is temperature-dependent and can change with changes in temperature. A decrease in temperature can cause the equilibrium to shift towards the reactants, while an increase in temperature can shift it towards the products. However, at any given temperature, a Keq value greater than 1 indicates that the reaction is proceeding towards the products side, and a Keq value less than 1 indicates that it is proceeding towards the reactants side.
In summary, a Keq value of 29 suggests that the products are strongly favored over the reactants at equilibrium, and the ratio of the concentration of products to the concentration of reactants is 29:1.
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13. In Singapore, the legal limit for the concentration of alcohol (ethanol, C,H,OH) in the blood is 80 mg in 100 cm³ of blood. Complete the table by calculating the concentration of alcohol in mol dm-3 in a person at various states of intoxication. You may assume that 1 dm³ of blood contains 1 dm³ of water.
The concentrations in mol/dm³ would be 0.002, 0.04, 0.007, and 0.01 respectively.
Concentration in mol/dm3Since 1 dm³ of blood is taken as containing 1 dm³ of water, it means that the concentration levels are in mg/dm³.
Thus, we are tasked with the job of converting from mg/dm³ to mol/dm³.
Recall that: mole = mass in grams/molar mass in gram/mole
Molar mass of ethanol = 46.07 g/mol
80 mg of ethanol = 0.08 g = 0.08/46.07 = 0.002 mol
200 mg of ethanol = 0.2 g - 0.2/46.07 = 0.004 mol
300 mg = 0.3 g = 0.3/46.07 = 0.007 mol
500 mg = 0.5 g = 0.5/46.07 = 0.01 mol
Therefore, the respective concentrations in mol/dm³ would be 0.002, 0.04, 0.007, and 0.01 respectively.
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A certain radionuclide is used to diagnose lymphoma. An atom of this radionuclide contains 31 protons and 36 neutrons. Which statement is correct about the radionuclide?
Answer:
A.The atomic number is 31, the mass number is 67, and its symbol is 67/31 GA.
Explanation:
Statements are:
A.The atomic number is 31, the mass number is 67, and its symbol is 67/31 GA.
B.The atomic number is 31, the mass number is 67, and its symbol is 31/64 GA.
C.The atomic number is 67, the mass number is 31, and its symbol is 67/31 GA .
D.The atomic number is 67, the mass number is 31, and its symbol is 31/64 GA .
Atomic number is defined as the number of protons in an atom. The radionuclide has 31 protons. Its atomic number is 31. C and D are FALSE
In the nuclear notation, in the top you have mass number = Sum of protons + neutrons = 67. And in the bottom you have atomic number = 31.
Thus, right statement is:
A.The atomic number is 31, the mass number is 67, and its symbol is 67/31 GA.
Answer:
A
Explanation:
Which of these is not a component of Rutherford’s model of the atom?
The Rutherford's model lacks an atom's electrical structure and electromagnetic radiation.
What elements make up Rutherford's atomic model?According to the idea, an atom has a tiny, compact, positively charged center called a nucleus, where almost all of the mass is concentrated, while light, negatively charged particles called Like planets circle the Sun, electrons also travel a great distance around it. Rutherford discovered that an atom's interior is mostly empty.
What does Rutherford's conclusion leave out?Rutherford's alpha scattering experiment did not come to any conclusions on how quickly positively charged particles travel. The nucleus, or core, of the atom contains the positively charged particles.
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plz someody help i need help for my quiz there gonna close ittt!!
What is the mass of 22 mL of gold, which has a density of 19.3 g/mL? Show your work or explain your steps.
Answer:
424.6g
Explanation:
Density is a measure of a substance's mass over its volume.
d = m/v
we can rearrange this equation to solve for mass algebraically.
dv = m
We can then substitute the given values for our variables in the problem and solve for our answer.
22mL(19.3g/mL)= 424.6g
Can you provide a simple diagram that would explain (why/how)the difference in boiling temperature between an alcohol and a diol?
Explanation:
Hydrogen bonding, present in alcohols but not hydrocarbons, leads to strong intermolecular forces and increases the boiling point significantly.
For example:
Glycerol has 3 OH groups, which lead to a much more extensive hydrogen-bonding network and a higher boiling point compared to the 1 OH or 2 OH in other chains.
True or false: animals use photosynthesis to make food
Two cars A and B are moving in opposite directions with the velocity of 20m/s and 6m/s respectively Calculate the relative of car A with respect to car B If they move in the same velocity what will be the relative velocity of CarA with respect to Car B
The relative velocity is described as the velocity of an object with respect to another viewer. It is the time rate of shift of relative position of one object with respect to another object.
How to find out the Relative Velocity of car A and car B ?a) Velocity of car A (Va) = 20m/s
Velocity of car B (Vb) = -6m/s
To find the Relative Velocity, we should apply the formula as,
Relative Velocity of car A and car B = Vab
Vab = Va - Vb
Vab = 20 - (-6)
Vab = 20+6
Vab = 26m/s
b). if Velocity of car A = Velocity of car B
Va = Vb
In this case,
Relative Velocity = Vab
Vab = Va - Vb
(since Va = Vb)
Vab = 0m/s
Hence, the Relative Velocity in a). is 26m/s and in b). is 0m/s.
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If I made any mistakes in this please tell me now
Answer:
no u did not u did good
Explanation:
If 26.5 L of nitrogen at 748 mm Hg are compressed to 765 mm Hg at constant temperature. What is the new volume?
Answer:
25.91 L
Explanation:
P1V1= P2V2
748 (26.5) = 765 ( V2) V2 = 25.91 LITERS
O2 transport in a person alternates between convection and diffusion. what best explains this pattern?
The pattern of alternating between convection and diffusion in O2 transport in a person can be attributed to the different methods by which O2 is transported in the body.
Convection refers to the movement of O2 through the bloodstream with the help of the circulatory system, while diffusion refers to the movement of O2 through the tissues and cells by means of diffusion gradients. During exercise or physical exertion, for example, the body may require more O2 than what can be supplied by convection alone. In these cases, diffusion plays a more significant role in O2 transport as it enables a greater amount of O2 to be delivered to the tissues and cells. Conversely, during rest or low levels of activity, convection may be the primary method of O2 transport as the body requires less oxygen. Therefore, the alternating pattern of convection and diffusion in O2 transport is a natural and necessary process that enables the body to efficiently deliver oxygen to where it is needed.
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What are 10 examples of homogeneous mixtures?
A homogeneous mixture is a mixture where the components are uniformly distributed throughout the mixture, resulting in a uniform composition and appearance. Here are 10 examples of homogeneous mixtures:
Saltwater: When salt is dissolved in water, the resulting mixture is homogeneous, with the salt molecules evenly distributed throughout the water.
Air: The air we breathe is a mixture of gases, including nitrogen, oxygen, and carbon dioxide. These gases are evenly distributed throughout the atmosphere, resulting in a homogeneous mixture.
Sugar solution: When sugar is dissolved in water, the resulting mixture is homogeneous, with the sugar molecules evenly distributed throughout the water.
Vinegar: Vinegar is a homogeneous mixture of acetic acid and water, with the two components evenly distributed throughout the solution.
Milk: Milk is a homogeneous mixture of water, fat, protein, and sugar, with these components evenly distributed throughout the liquid.
Brass: Brass is a homogeneous mixture of copper and zinc, with the two metals evenly distributed throughout the alloy.
Gasoline: Gasoline is a homogeneous mixture of hydrocarbons and other additives, with the components evenly distributed throughout the liquid.
Blood: Blood is a homogeneous mixture of plasma, red and white blood cells, and platelets, with these components evenly distributed throughout the liquid.
Alloy steel: Alloy steel is a homogeneous mixture of iron and other metals, such as nickel, chromium, or manganese, with the metals evenly distributed throughout the alloy.
Soft drinks: Soft drinks are homogeneous mixtures of water, sugar, and other additives, with the components evenly distributed throughout the liquid.
Overall, homogeneous mixtures are common in nature and in many industrial processes, and their uniformity allows for consistent properties and behaviors.
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Where can I find theses worksheets and tests?
Answer:
Here
Explanation:
Please respond to each of the following questions by the due date. You must then respond to each of your group peers within -3 days after the due date (please see the printable course schedule in the syllabus). Remember that the response part of the assignment will NOT appear on the ToDo list, so you must keep track of and beware of these assignments on your own. In the early 1950s, it became clear to many researchers that DNA was the cellular molecule that carries genetic information. However, an understanding of the genetic properties of DNA could only be achieved through a detailed knowledge of its structure. To this end, several laboratories began a highly competitive race to discover the three-dimension structure of DNA, which ended when Watson and Crick published their now classic paper in 1953. Their model was based, in part, on an X-ray diffraction photograph of DNA taken by Rosalind Franklin. Two ethical issues surround this photo. First, the photo was given to Watson and Crick by Franklin's co-worker, Maurice Wilkins, without her knowledge or consent. Second, in their paper, Watson and Crick did not credit Franklin's contribution. The fallout from these lapses lasted for decades an raises some basic questions about ethics in science. 1. What vital clues were provided by Franklin's work to Watson and Crick about the molecular structure of DNA? 2. Was it ethical for Wilkins to show Franklin's unpublished photo to Watson and Crick without Franklin's consent? Would it have been more ethical for Watson and Crick to have offered Franklin co-authorship on this paper? 3. Given that these studies were conducted in the 1950s, how might gender have played a role in the fact that Rosalind Franklin did not receive credit for her X-ray diffraction work?
The vital clues that were provided by Franklin's work to Watson and Crick about the molecular structure of DNA:Rosalind Franklin's research played an important role in understanding the structure of DNA. X-ray crystallography was used by Franklin to study the arrangement of atoms in DNA molecules.
When Franklin's photos were studied by Watson and Crick, they discovered that the DNA molecule had a double helix shape. This discovery allowed them to make a model of the DNA structure that was later confirmed.2. It was not ethical for Wilkins to show Franklin's unpublished photo to Watson and Crick without Franklin's consent. Even though Wilkins was Franklin's co-worker, the photo was Franklin's intellectual property, and he had no right to share it with others. Watson and Crick should have acknowledged Franklin's contribution in their research.
Franklin's work was crucial to the discovery of the DNA structure, and she should have been given credit. Watson and Crick should have offered her co-authorship on the paper.3. Gender may have played a role in the fact that Rosalind Franklin did not receive credit for her X-ray diffraction work. Women in science were not treated equally to men in the 1950s. Franklin was not offered the same opportunities as Watson and Crick, despite her important contributions to their research. It is likely that her gender was a factor in her treatment. Today, the scientific community recognizes the importance of diversity in science, and steps are being taken to ensure that all scientists are treated equally.
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How many Liters of Oxygen gas is used from 45.3g of MnO3?
Liters of Oxygen = 11.5 liters of Oxygen gas produced from 45.3g of MnO3.
What is oxygen gas?Oxygen gas (O2) is a colorless, odorless, tasteless gas that is essential for life on Earth. It makes up about 21% of the air we breathe and is the most abundant element in the Earth's atmosphere. Oxygen gas is highly reactive and participates in many chemical reactions, including combustion and respiration. In combustion, oxygen gas combines with other elements such as carbon, hydrogen, and other compounds to form oxides and release energy as heat. In respiration, oxygen gas is used by cells to produce energy.
Manganese trioxide (MnO3) is an inorganic compound composed of manganese and oxygen atoms. When MnO3 is heated, it will produce oxygen gas. The amount of oxygen gas produced from 45.3g of MnO3 can be calculated using the following equation:
Moles of Oxygen = 45.3g/Molecular Weight of MnO3
Molecular Weight of MnO3 = 87.9g/mol
Moles of Oxygen = 0.517 mol
Liters of Oxygen = 0.517 mol x 22.4 L/mol
Liters of Oxygen = 11.5 liters of Oxygen gas produced from 45.3g of MnO3.
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Which substance is the oxidizing agent in the reaction below? Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O A.Pb B.PbSO4
C. H20
D. H2SO4 E.PbO2
The substance that is the oxidizing agent in the reaction is E.\(PbO2\)
A chemical species known as an oxidizing agent has a propensity to oxidise other compounds. This indicates that it causes a material to become more oxidised by causing it to lose electrons. Normal oxidising agents live in their most oxidized forms and have a significant propensity to pick up electrons and proceed through reduction. Strongly electron-affine ions, atoms, and molecules are regarded as effective oxidizers. The power of oxidation increases with increasing electron affinity.
Pb is the chemical that undergoes a reduction in the process, changing its oxidation state from 0 to +2 in the formation of \(PbSO4\). The oxidising agent is the chemical that results in the reduction of Pb. \(PbO2\) serves as the oxidising agent in this situation because it contributes oxygen atoms to the oxidation process.
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Andy made the following list to describe one of the weather components:
It is moving air.
It is measured in miles per hour.
Letter symbols indicate where it is coming from.
Which weather component is Andy describing?
Air pressure
Air temperature
Humidity
Wind
Answer:
Th answer is wind
Explanation:
Dont remove this
Answer:
Air pressure
Explanation:
I did the test
Arrange the following element, lithium, potassium, carbon and fluorine in increasing ionization energy
Answer:
flourine(1681),carbon(1086),lithium(520) and potassium(419)
as we can see that the ionization energy of flourine is the highest than carbon than lithium and than potassium
Explanation:
i hope it will help you
Answer:
Potassium, Lithium, Carbon, Fluorine
Explanation:
potassium has the least and Fluorine has the most
When a piston is pushed down on a cylinder, the pressure on the gas in the cylinder increases from 125 kPa to 375 kPa. The initial volume is 3.3 L. What is the final volume?
Answer:
The final volume is 1.1 L.
Explanation:
Given data:
Initial pressure of gas = 125 KPa
Final pressure of gas = 375 KPa
Initial volume = 3.3 L
Final volume = ?
Solution:
The given problem will be solved through the Boly's law,
"The volume of given amount of gas is inversely proportional to its pressure by keeping the temperature and number of moles constant"
Mathematical expression:
P₁V₁ = P₂V₂
P₁ = Initial pressure
V₁ = initial volume
P₂ = final pressure
V₂ = final volume
Now we will put the values in formula,
P₁V₁ = P₂V₂
125 Kpa × 3.3 L = 375 Kpa × V₂
V₂ = 412.5 KPa. L/375 Kpa
V₂ = 1.1 L
The volume of gas is reduced to the 1.1 L because of increasing pressure.
Cuando se queman combustibles que tienen algún compuesto de azufre se produce dióxido de azufre (SO2), un gas irritante que puede provocar lluvia ácida. En el análisis del aire de una ciudad se ha encontrado una concentración de SO2 de 14 mg/m^3 ¿Qué cantidad de SO2 habrá en 1 L de aire?
Answer:
See answer below
Explanation:
I have to answer this question in english because is the rule here. I hope you can understand this.
Now, in order to answer this, is really easy. We already have the quantity of SO₂ in the air of a city. This concentration is 14 mg/m³, so we want to know the quantity in 1 L. This quantity can be expressed in mass.
If concentration according to the units is: mg/m³ This means that we have units of mass and volume. So, in order to know the quantity of SO₂ in mass, we need to convert the units of volume m³ to liter.
1 m³ is covered in 1000 L, therefore:
14 mg/m³ * 1 m³/1000 L = 0.014 mg/L
Then, the mass will be:
m = 0.014 mg/L * 1 L
m = 0.014 mg of SO₂
This is the quantity of SO₂ in 1 L.